CHEMICALS DIVISION - CELANESE, LTD -- 227711,ETHYL ACETATE -- 6810-00-245-6695
===================== Product Identification ===================== Product ID:227711,ETHYL ACETATE MSDS Date:04/17/2000 FSC:6810 NIIN:00-245-6695 === Responsible Party === Company Name:CHEMICALS DIVISION - CELANESE, LTD Address:1601 W LBJ FREEWAY Box:819005 City:DALLAS State:TX ZIP:75381-9005 Country:US Info Phone Num:972-443-4000 Emergency Phone Num:800-835-5235 Resp. Party Other MSDS Num.:34 Preparer's Name:NOT PROVIDED Chemtrec Ind/Phone:(800)424-9300 CAGE:TO903 === Contractor Identification === Company Name:CELANESE CANADA, INC Address:STATION MAIN Box:99 City:EDMONTON, ALBERTA, CANADA Phone:780-471-0425 CAGE:TO068 Company Name:CHEMICALS DIVISION - CELANESE, LTD Address:1601 W LBJ FREEWAY Box:819005 City:DALLAS State:TX ZIP:75381-9005 Country:US Phone:972-443-4000 CAGE:TO903 Company Name:INDUSTRIAL CHEMICAL COMMODITIES INC Address:15944 DERWOOD RD Box:City:ROCKVILLE State:MD ZIP:20855 Country:US Phone:800-284-5279 Contract Num:SP0450-00-M-SF78 CAGE:1ELU0 Company Name:VAN WATERS & ROGERS City:MORRISVILLE Phone:000-000-0000 CAGE:TO890 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ACETATE CAS:141-78-6 RTECS #:AH5425000 = Wt:99.5 Other REC Limits:NOT PROVIDED OSHA PEL:1400 MG/M3;400 PPM ACGIH TLV:1440 MG/M3;400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50: 5620 TO 10170 MG/KG (RATS). Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:IMMEDIATE EFFECTS: SKIN: REPEATED OR PROLONGED CONTACT CAN CAUSE DRYING OF SKIN. EYES: VAPOR AND LIQUID ARE IRRITATING TO THE EYES. INHALATION: VAPORS ARE IRRITATING TO NASAL PASSAGES AND THROAT. HIGH CONCENTRATIONS CAN CAUSE STUPOR AND HEADACHES. INGESTION: CAN CAUSE HEADACHE, DROWSINESS AND UNCONSCIOUSNESS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: REPEATED OR PROLONGED CONTACT CAN CAUSE DRYING OF SKIN. EYES: VAPOR AND LIQUID ARE IRRITATING TO THE EYES. INHALATION: VAPORS ARE IRRITATING TO NASAL PASSAGES AND THROAT. HIGH CONCENTRATIONS CAN CAUSE STUPOR AND HEADACHES. INGESTION: CAN CAUSE HEADACHE, DROWSINESS AND UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:SIGNIFICANT EXPOSURE TO THIS CHEMICAL MAY ADVERSELY AFFECT PEOPLE WITH CHRONIC DISEASE OF THE RESPIRATORY SYSTEM, SKIN AND/ OR EYES. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMINATED CLOTHING AND WASH CONTAMINATED SKIN WITH LARGE AMOUNT OF SOAP AND WATER. IF IRRITATION PERSISTS, CONTACT A PHYSICIAN. EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CONTACT A PHYSICIAN. INHALATION: REMOVE PATIENT FROM CONTAMINATED AREA. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION, THEN OXYGEN IF NEEDED. CONTACT A PHYSICIAN IMMEDIATE LY. INGESTION: INDUCE VOMITING OF CONSCIOUS PATIENT IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND PRESSING FINGER DOWN THROAT. CONTACT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=-4.4C, 24.F Lower Limits:2.0 Upper Limits:11.4 Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES; ALCOHOL TYPE AQUEOUS FILM-FORMING FOAM OR WATER SPRAY FOR LARGE FIRES. WATER MAY BE INEFFECTIVE BUT SHOULD BE USED TO COOL CONTAINERS. Fire Fighting Procedures:IF POTENTIAL FOR EXPOSURE TO VAPORS/COMBUSTION PRODUCTS EXISTS, WEAR PERSONAL PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN PRESSURE DEMAND/POSITI VE PRESSURE MODE. VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK Unusual Fire/Explosion Hazard:MATERIAL CREATES A SPECIAL HAZARD BECAUSE IT FLOATS ON WATER. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT. AVOID CONTACT. PLACE LEAKING CONTAINERS IN WELL VENTILATED AREA WITH SPILL CONTAINMENT. IF FIRE POTENTIAL EXISTS, BLANKET SPILL WITH ALCOHOL-TYPE AQUEOUS FILM FORMING FOAM/USE WATER SPRAY TO DISPERSE VAPORS. CONTAIN SPILL. USE ABSORBENT MATERIALS OR VACUUM TRUCK. AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO NATURAL WATERWAYS. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP ALL CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. STORE OUT OF DIRECT SUNLIGHT AND ON AN IMPERMEABLE FLOOR. DO NOT STORE WITH INCOMPATIBLE MATERIALS. ALWAYS OPEN CONTAINERS SLOWLY TO ALLOW ANY EXCES S PRESSURE TO VENT. Other Precautions:AVOID BREATHING VAPOR. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. DECONTAMINATE SOILED CLOTHING THOROUGHLY BEFORE REUSE. DESTROY CONTAMINATED LEATHE R CLOTHING. USE WITH ADEQUATE VENTILATION.. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:BASED ON WORKPLACE CONTAMINATE LEVEL AND WORKING LIMITS OF RESPIRATOR, USE A RESPIRATOR APPROVED BY NIOSH/MSHA. USE AIR-PURIFYING RESPIRATOR WITH FULL FACEPIECE AND ORGANIC VAPOR CARTRIDGE/CANISTER. F OR CONCENTRATIONS >=100 TIMES ACCEPTABLE LEVEL/UNKNOWN (SUCH AS IN EMERGENCIES), USE SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE IN PRESSURE-DEMAND. Ventilation:GENERAL OR DILUTION VENTILATION FREQUENTLY INSUFFICIENT. LOCAL VENTILATION IS USUALLY PREFERRED. EXPLOSION PROOF EQUIPMENT SHOULD BE USED. Protective Gloves:WEAR BUTYL RUBBER GLOVES TO PREVENT REPEATED OR PROLONGED CONTACT. Eye Protection:WEAR CHEMICAL GOGGLES WHEN THERE IS A REASONABLE CHANCE OF EYE CONTACT. Other Protective Equipment:IMPERVIOUS CLOTHING Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=77.C, 170.6F Melt/Freeze Pt:=-83.C, -117.4F Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:73 @ 20C/68F Vapor Density:3.0 Spec Gravity:0.901 pH:NOT RELEVANT Viscosity:NOT PROVIDED Evaporation Rate & Reference:4.5 (BUAC=1) Solubility in Water:8.7 % Appearance and Odor:CLEAR, COLORLESS MOBILE LIQUID; STRONG FRUITY ODOR Percent Volatiles by Volume:100 Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS SUCH AS HYDROGEN PEROXIDE, NITRIC ACID, PERCHLORIC ACID OR CHROMIUM TRIOXIDE. Stability Condition to Avoid:HEAT, SPARKS, FLAME. Hazardous Decomposition Products:CARBON MONOXIDE =================== Toxicological Information =================== Toxicological Information:ACUTE EXPOSURE: ORAL LD50: 5620 TO 10170 MG/KG (RATS); ETHYL ACETATE IS PRACTICALLY NONTOXIC TO ANIMALS BY INGESTION. INHALATION: LC50: 200 MG/L (RATS, 1 HR.): INHALATION: LC50: >29.3 MG/L (RATS, 4 HR S.); ETHYL ACETATE IS PRACTICALLY NONTOXIC TO ANIMALS BY INHALATION. SEDATIVE EFFECTS HAVE BEEN OBSERVED IN ANIMALS. MILD NOSE AND THROAT IRRITATION HAVE BEEN REPORTED IN HUMANS AT 400 PPM. DERMAL LD5 0, RABBITS: >5000 MG/KG. PRACTICALLY NONTOXIC DERMALLY TO ANIMALS. MILD EYE IRRITATION HAVE BEEN REPORTED IN HUMANS AT 400 PPM. ===================== Ecological Information ===================== Ecological:ETHYL ACETATE EXHIBITS LOW ACUTE TOXICITY TO AQAUTIC ORGANISMS. ETHYL ACETATE WAS "READILY BIODEGRADABLE" WHEN TESTED. SUBSTANTIAL BIODEGRRADATION TAKES PLACE RAPIDLY UNDER A VARIETY OF CONDITIONS. PH OTODEGRADATION TESTS INDICATE THAT BOTH DIRECT AND INDIRECT PHOTOLYSIS CAN OCCUR, WITH RESULTS VARIABLE DEPENDING UPON THE TEST CONDITIONS. ETHYL ACETATE HAS LOW POTENTIAL TO BIOACCUMULATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL NOTIFICATION, CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. PREFERRED METHODS OF WASTE DISPOSAL ARE INCINERATION OR BIOLOGICAL TREATMENT IN F EDERAL/STATE APPROVED FACILITY. HAZARDOUS WASTE (40 CFR 261): YES: U112, D001. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME: ETHYL ACETATE. HAZARD CLASS: 3, FLAMMABLE LIQUID. UNITED NATION NO: UN1173. PACKING GROUP: I I. DOT REPORTABLE QUANTITY (RQ): 5000 LBS/2270 KG. TRANSPORTATION OF DANGEROUS GOODS CODES: CLASSIFICATION: FLAMMABLE LIQUID, 3. ===================== Regulatory Information ===================== SARA Title III Information:SARA 311: ACUTE HEALTH: YES, CHRONIC HEALTH: NO. FIRE: YES, SUDDEN RELEASE OF PRESSURE: NO, REACTIVE: NO. SARA 304: ETHYL ACETATE 99.5% (141-78-6). Federal Regulatory Information:WE CERTIFY THAT ALL COMPONENTS ARE EITHER ON THE TSCA INVENTORY OR ARE QUALIFY FOR AN EXEMPTION. ENVIRONMENTAL: CERCLA: ETHYL ACETATE 99.5% (141-78-6). State Regulatory Information:THE FOLLOWING CHEMICALS ASSOCIATED WITH THE PRODUCT ARE SUBJECT TO THE RIGHT-TO-KNOW REGULATIONS IN THESE STATES: ETHYL ACETATE (141-78-6): CT, FL, IL, MA, NJ, NY, PA, RI. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.